Mesostructure controllable ZSM-5 single crystals supported Pd/transition metal oxides: efficient and reusable catalysts for selective oxidation under aerobic conditions

• Published in: Journal of porous materials Vol. 24; no. 2; pp. 297 - 303
• Main Authors: Liu, Chen, Wu, Qin, Peng, Jinjun, Qi, Chenze, Liu, Fujian
• Format: Journal Article
• Language: English
• Published: New York Springer US 01.04.2017; Springer Nature B.V
• Subjects: Activated carbon; Alcohols; Aluminosilicates; Aluminum silicates; Catalysis; Catalysts; Cationic; Cationic polymerization; Characterization and Evaluation of Materials; Chemistry; Chemistry and Materials Science; Crystallization; Gels; Metal oxides; MOX; Oxidation; Palladium; Physical Chemistry; Porosity; Silicon dioxide; Single crystals; Solvents; Transition metal oxides; Transition metals; Self assembly; Reusability; Transition metal catalysis; Mesoporous zeolites; Aerobic oxidation

Pd and transition metal oxides functionalized ZSM-5 single crystals with b -axis aligned mesopores (ZSM-5-OM-PdO x -MO x ) were prepared. ZSM-5-OM support was obtained from crystallization of aluminosilicate gels in the presence of cationic polymers. Characterizations indicate abundant nanopores and...