Mesostructure controllable ZSM-5 single crystals supported Pd/transition metal oxides: efficient and reusable catalysts for selective oxidation under aerobic conditions
Pd and transition metal oxides functionalized ZSM-5 single crystals with b -axis aligned mesopores (ZSM-5-OM-PdO x -MO x ) were prepared. ZSM-5-OM support was obtained from crystallization of aluminosilicate gels in the presence of cationic polymers. Characterizations indicate abundant nanopores and...
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Published in | Journal of porous materials Vol. 24; no. 2; pp. 297 - 303 |
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Main Authors | , , , , |
Format | Journal Article |
Language | English |
Published |
New York
Springer US
01.04.2017
Springer Nature B.V |
Subjects | |
Online Access | Get full text |
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Summary: | Pd and transition metal oxides functionalized ZSM-5 single crystals with
b
-axis aligned mesopores (ZSM-5-OM-PdO
x
-MO
x
) were prepared. ZSM-5-OM support was obtained from crystallization of aluminosilicate gels in the presence of cationic polymers. Characterizations indicate abundant nanopores and highly crystalline degree of ZSM-5-OM-PdO
x
-MO
x
, and active species of Pd and transition metals were homogeneously dispersed into ZSM-5-OM, which showed unique interactions and enhanced ability for activating oxygen. Catalytic tests showed that ZSM-5-OM-PdO
x
-MO
x
were highly active and reusable catalysts for selective oxidation of alcohols under aerobic and solvent free condition, which were much better than those of Pd/transition metal oxides functionalized ZSM-5, mesoporous silica of SBA-15, and activated carbon catalysts. |
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Bibliography: | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
ISSN: | 1380-2224 1573-4854 |
DOI: | 10.1007/s10934-016-0263-3 |