Rhodium(i), rhodium(iii) and iridium(iii) carbaporphyrins

Treatment of a benzocarbaporphyrin with [Rh(CO)2Cl]2 in refluxing dichloromethane gave a rhodium(i) dicarbonyl complex, and further reaction in refluxing pyridine afforded an organometallic rhodium(iii) derivative. The carbaporphyrin also reacted with [Ir(COD)Cl]2 and pyridine in refluxing p-xylene...

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Published inDalton transactions : an international journal of inorganic chemistry Vol. 45; no. 35; pp. 13691 - 13694
Main Authors Adiraju, Venkata A K, Ferrence, Gregory M, Lash, Timothy D
Format Journal Article
LanguageEnglish
Published England 01.01.2016
Subjects
Derivatives
Dichloromethane
Metalorganic compounds
Pyridines
Refluxing
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Summary:Treatment of a benzocarbaporphyrin with [Rh(CO)2Cl]2 in refluxing dichloromethane gave a rhodium(i) dicarbonyl complex, and further reaction in refluxing pyridine afforded an organometallic rhodium(iii) derivative. The carbaporphyrin also reacted with [Ir(COD)Cl]2 and pyridine in refluxing p-xylene to generate a related iridium(iii) compound. These novel metalated porphyrinoids retained strongly diatropic characteristics and were fully characterized by XRD.
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ISSN:1477-9226
1477-9234
DOI:10.1039/c6dt03093a