Tetrathiafulvalene-annulated [28]hexaphyrin(1.1.1.1.1.1): a multi-electron donor system subject to conformational control

Tetrathiafulvalenes (TTF)-annulated [28]hexaphyrin affords an electron rich flexible pi-conjugated system whose limiting conformations can be controlled through choice of solvents. The conformation-dependent intramolecular charge transfer character, as well as electron reserve capability of the hexa...

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Published inChemical communications (Cambridge, England) Vol. 49; no. 79; pp. 8937 - 8939
Main Authors Jana, Atanu, Ishida, Masatoshi, Cho, Kevin, Ghosh, Sudip Kumar, Kwak, Kyuju, Ohkubo, Kei, Sung, Young Mo, Davis, Christina M., Lynch, Vincent M., Lee, Dongil, Fukuzumi, Shunichi, Kim, Dongho, Sessler, Jonathan L.
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 01.01.2013
Subjects
Charge transfer
chemical communication
chemical compounds
chemical reactions
Chemistry
Chemistry, Multidisciplinary
Constraining
Control systems
Crystallography, X-Ray
Cyclization
Electrochemical Techniques
Electrons
Heterocyclic Compounds - chemistry
Heterocyclic Compounds, 2-Ring - chemical synthesis
Heterocyclic Compounds, 2-Ring - chemistry
Molecular Conformation
Oxidation-Reduction
Physical Sciences
Porphyrins - chemical synthesis
Porphyrins - chemistry
Reserves
Science & Technology
Solvents
Solvents - chemistry
PORPHYRINS
COMPLEXES
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Summary:Tetrathiafulvalenes (TTF)-annulated [28]hexaphyrin affords an electron rich flexible pi-conjugated system whose limiting conformations can be controlled through choice of solvents. The conformation-dependent intramolecular charge transfer character, as well as electron reserve capability of the hexakis-TTF annulated hexaphyrin, was analyzed.
Bibliography:National Science Foundation
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1359-7345
1364-548X
1364-548X
DOI:10.1039/c3cc44934c