Programmable self-assembly of water-soluble organo-heterometallic cages [M 12 M' 4 L 12 ] using 3-(3,5-dimethyl-1H-pyrazol-4-yl)pentane-2,4-dione (H 2 L)
A bifunctional ligand H L featuring primary (pyrazole) and secondary (acetylacetone) coordination sites was preferentially reacted with dimetallic [M (NO ) ](NO ) linkers at the pyrazolyl end of H L, giving rise to dimetallic corners. Subsequently, the corners serve as the secondary site with M'...
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Published in | Chemical communications (Cambridge, England) Vol. 53; no. 30; pp. 4238 - 4241 |
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Main Authors | , , , , |
Format | Journal Article |
Language | English |
Published |
England
2017
|
Subjects | |
Online Access | Get full text |
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Summary: | A bifunctional ligand H
L featuring primary (pyrazole) and secondary (acetylacetone) coordination sites was preferentially reacted with dimetallic [M
(NO
)
](NO
)
linkers at the pyrazolyl end of H
L, giving rise to dimetallic corners. Subsequently, the corners serve as the secondary site with M' to form water-soluble organo-heterometallic [M
M'
L
] cages in a stepwise mode. |
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Bibliography: | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
ISSN: | 1359-7345 1364-548X |
DOI: | 10.1039/c7cc00425g |