Organogelators of 5,17-Difunctionalized Calix[4]arenes

5,17-Difunctionalized calix[4]arenes 1a,b were found to function as low molecular-weight organic gelators. They formed organogels with a variety of organic solvents. SEM images showed 1a formed stacked structures in the xerogels. Single-crystal X-ray analysis of 1c as well as AFM, XRD, and SAXS meas...

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Bibliographic Details
Published inChemistry letters Vol. 48; no. 1; pp. 43 - 46
Main Authors Duy, Lai Nang, Sekiya, Ryo, Tosaka, Masatoshi, Yamago, Shigeru, Matsumoto, Takuya, Nishino, Takashi, Ichikawa, Takayuki, Haino, Takeharu
Format Journal Article
LanguageEnglish
Published TOKYO Chemical Soc Japan 05.01.2019
Subjects
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
ARENE
DESIGN
Soft material
MOLECULAR RECOGNITION
Calixarene
SUPRAMOLECULAR GELS
CALIXARENE-BASED GELATORS
Organogel
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Summary:5,17-Difunctionalized calix[4]arenes 1a,b were found to function as low molecular-weight organic gelators. They formed organogels with a variety of organic solvents. SEM images showed 1a formed stacked structures in the xerogels. Single-crystal X-ray analysis of 1c as well as AFM, XRD, and SAXS measurements of 1a indicated that the xerogels contained lamellar structures of the calix[4]arenes.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.180819