Topochemical synthesis of cation ordered double perovskite oxynitrides

Topochemical nitridation in ammonia at moderate temperatures of cation ordered Sr FeWO produces new antiferromagnetic double perovskite oxynitrides Sr FeWO N with 0 < x ≤ 1. Nitrogen introduction induces the oxidation of Fe to Fe and decreases T from 38 K (x = 0) to 13 K for Sr FeWO N which repre...

Full description

Saved in:
Bibliographic Details
Published inDalton transactions : an international journal of inorganic chemistry Vol. 46; no. 16; pp. 5128 - 5132
Main Authors Ceravola, Roberta, Oró-Solé, Judith, Black, Ashley P, Ritter, Clemens, Puente Orench, Inés, Mata, Ignasi, Molins, Elies, Frontera, Carlos, Fuertes, Amparo
Format Journal Article
LanguageEnglish
Published England 2017
Subjects
Ammonia
Antiferromagnetism
Cationic
Cations
Nitrogen
Oxynitrides
Perovskites
Synthesis
Online AccessGet full text

Cover

More Information
Summary:Topochemical nitridation in ammonia at moderate temperatures of cation ordered Sr FeWO produces new antiferromagnetic double perovskite oxynitrides Sr FeWO N with 0 < x ≤ 1. Nitrogen introduction induces the oxidation of Fe to Fe and decreases T from 38 K (x = 0) to 13 K for Sr FeWO N which represents the first example of a double perovskite oxynitride with both high cationic order and nitrogen content. This synthetic approach can be extended to other cation combinations expanding the possibility of new materials in the large group of double perovskites.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1477-9226
1477-9234
DOI:10.1039/c7dt00800g