Lanthanide separation using size-selective crystallization of Ln-MOFs

Herein, we report an elaborate method, size-selective crystallization of Ln-MOFs, to isolate lanthanide (Ln) ions. Herein, 13 lanthanide ions, except for the radioactive Pm(iii) ion, were separated by four types of Ln-MOFs: type I (La-Pr), type II (Nd-Eu), type III (Gd-Ho), and type IV (Er-Lu). Furt...

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Published inChemical communications (Cambridge, England) Vol. 53; no. 42; pp. 5737 - 5739
Main Authors Ya Gao, Heng, Li Peng, Wen, Pan Meng, Pan, Feng Feng, Xue, Qiang Li, Jian, Qiong Wu, Hui, Sheng Yan, Chang, Yang Xiong, Yang, Luo, Feng
Format Journal Article
LanguageEnglish
Published England 2017
Subjects
Crystallization
Lanthanides
Separation
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Summary:Herein, we report an elaborate method, size-selective crystallization of Ln-MOFs, to isolate lanthanide (Ln) ions. Herein, 13 lanthanide ions, except for the radioactive Pm(iii) ion, were separated by four types of Ln-MOFs: type I (La-Pr), type II (Nd-Eu), type III (Gd-Ho), and type IV (Er-Lu). Further systemic investigation also suggested the highly selective separation of lanthanide ions by this method.
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ISSN:1359-7345
1364-548X
DOI:10.1039/c7cc01898c