Pillar[5]arene-based polymeric architectures constructed by orthogonal supramolecular interactions

Ureidopyrimidinone functionalized pillar[5]arene (UPyP5) was synthesized and employed to complex with a bisparaquat derivative (G) to form supramolecular polymers at relatively high concentration. The orthogonal binding interactions including quadruple hydrogen bonding and host-guest interaction sho...

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Published inChemical communications (Cambridge, England) Vol. 48; no. 68; pp. 8529 - 8531
Main Authors Guan, Yangfan, Ni, Mengfei, Hu, Xiaoyu, Xiao, Tangxin, Xiong, Shuhan, Lin, Chen, Wang, Leyong
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 01.01.2012
Subjects
Architecture
aromatic hydrocarbons
Assembly
Binding
chemical communication
chemical reactions
Chemistry
Chemistry, Multidisciplinary
Construction
Derivatives
Hydrogen bonding
Physical Sciences
polymers
Science & Technology
Supramolecular polymers
ORGANIZATION
MONOMERS
CHEMISTRY
CROWN-ETHER
DRIVEN
COMBINATION
BINDING
HOST-GUEST COMPLEXATION
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Summary:Ureidopyrimidinone functionalized pillar[5]arene (UPyP5) was synthesized and employed to complex with a bisparaquat derivative (G) to form supramolecular polymers at relatively high concentration. The orthogonal binding interactions including quadruple hydrogen bonding and host-guest interaction should play vital roles in the construction of this linear assembly.
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ISSN:1359-7345
1364-548X
1364-548X
DOI:10.1039/c2cc33943a