Programmable self-assembly of homo- or hetero-metallomacrocycles using 4-(1H-pyrazolyl-4-yl)pyridine

The dimetallic [M(2)(bpy)(2)(NO(3))(2)](NO(3))(2) moieties (M = Pd(II) or Pt(II)) react preferentially at the pyrazolyl end of the pyridyl-pyrazole ligand, giving rise to dimetallic corners. Subsequently, the dimetallic corner building blocks featuring two pyridine donors are coordinated by monometa...

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Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 48; no. 43; pp. 5343 - 5345
Main Authors Tong, Jin, Yu, Shu-Yan, Li, Hui
Format Journal Article
LanguageEnglish
Published England 01.01.2012
Subjects
Corners
Ligands
Pyridines
Self assembly
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Summary:The dimetallic [M(2)(bpy)(2)(NO(3))(2)](NO(3))(2) moieties (M = Pd(II) or Pt(II)) react preferentially at the pyrazolyl end of the pyridyl-pyrazole ligand, giving rise to dimetallic corners. Subsequently, the dimetallic corner building blocks featuring two pyridine donors are coordinated by monometallic [M(bpy)(NO(3))(2)] moieties (M = Pd(II) or Pt(II)) to form homo- or hetero-metallomacrocycles.
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ISSN:1359-7345
1364-548X
DOI:10.1039/c2cc31234d