Ruthenium-catalyzed double-fold C-H tertiary alkoxycarbonylation of arenes using di-tert-butyl dicarbonate

An efficient ruthenium-catalyzed double-fold C-H alkoxycarbonylation of arenes was developed using di-tert-butyl dicarbonate as the tertiary esterification reagent, which leads to a direct route to valuable 2,6-dicarboxylated products.

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Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 50; no. 91; pp. 14129 - 14132
Main Authors Hong, Xiaohu, Wang, Hao, Liu, Bingxin, Xu, Bin
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 01.01.2014
Subjects
Aromatic compounds
Benzene Derivatives - chemical synthesis
Benzene Derivatives - chemistry
Carbonates - chemistry
Catalysis
Chemistry
Chemistry, Multidisciplinary
Esterification
Molecular Structure
Organometallic Compounds - chemistry
Physical Sciences
Reagents
Ruthenium - chemistry
Science & Technology
DIRECTING GROUP
FUNCTIONALIZATION
ORGANIC-SYNTHESIS
ACTIVATION
CONVENIENT METHOD
ESTERS
CALCIUM HALIDES
BONDS EFFICIENT ACCESS
CARBON-HYDROGEN BONDS
CLEAVAGE
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Summary:An efficient ruthenium-catalyzed double-fold C-H alkoxycarbonylation of arenes was developed using di-tert-butyl dicarbonate as the tertiary esterification reagent, which leads to a direct route to valuable 2,6-dicarboxylated products.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1359-7345
1364-548X
DOI:10.1039/c4cc05173d