Chiral template induced homochiral MOFs built from achiral components: SHG enhancement and enantioselective sensing of chiral alkamines by ion-exchange

A pair of chiral template induced anionic homochiral frameworks constructed from achiral components has been synthesized. Ion-exchange of counter cations with polar or chiral organic cations enhances the SHG efficiency of the frameworks. The enantioselective sensing of chiral alkamines can be achiev...

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Published inChemical communications (Cambridge, England) Vol. 51; no. 77; pp. 14481 - 14484
Main Authors Han, Yun-Hu, Liu, Yue-Cheng, Xing, Xiu-Shuang, Tian, Chong-Bin, Lin, Ping, Du, Shao-Wu
Format Journal Article
LanguageEnglish
Published England 01.01.2015
Subjects
Cations
Construction
Detection
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Summary:A pair of chiral template induced anionic homochiral frameworks constructed from achiral components has been synthesized. Ion-exchange of counter cations with polar or chiral organic cations enhances the SHG efficiency of the frameworks. The enantioselective sensing of chiral alkamines can be achieved by the SHG response.
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ISSN:1359-7345
1364-548X
DOI:10.1039/c5cc05566k