Repetitive stepwise rotaxane formation toward programmable molecular arrays

We present a novel strategy to synthesize multi-molecular arrays in a programmable way by stepwise elongation based on repetition of two-fold rotaxane formation and construction of threads. A cofacially triply stacked porphyrin array was obtained via the repetitive two-fold rotaxane formation.

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Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 49; no. 94; pp. 11053 - 11055
Main Authors Yamada, Yasuyuki, Okada, Masa-aki, Tanaka, Kentaro
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 01.01.2013
Subjects
Arrays
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
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Summary:We present a novel strategy to synthesize multi-molecular arrays in a programmable way by stepwise elongation based on repetition of two-fold rotaxane formation and construction of threads. A cofacially triply stacked porphyrin array was obtained via the repetitive two-fold rotaxane formation.
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ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc46859c