Molecular Structure and Theoretical Studies of (PPh₄)₂[Bi₁₀Cu₁₀(SPh)₂₄]

Shielded bismuth chains: The reaction of Bi(SPh)3 with CuSPh in the presence of PPh4Cl and PhSSiMe3 produced the title cluster (see picture of the cluster core; Bi red, Cu blue, S yellow). A surprising structural feature is the branched Bi10 chain, which exhibits a structure expected for a neutral a...

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Published inAngewandte Chemie (International ed.) Vol. 46; no. 43; pp. 8254 - 8257
Main Authors Ahlrichs, Reinhart, Eichhöfer, Andreas, Fenske, Dieter, May, Klaus, Sommer, Heino
Format Journal Article
LanguageEnglish
Published Weinheim Wiley-VCH Verlag 2007
WILEY-VCH Verlag
WILEY‐VCH Verlag
Subjects
bismuth
cluster compounds
copper
density functional calculations
sulfur
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Summary:Shielded bismuth chains: The reaction of Bi(SPh)3 with CuSPh in the presence of PPh4Cl and PhSSiMe3 produced the title cluster (see picture of the cluster core; Bi red, Cu blue, S yellow). A surprising structural feature is the branched Bi10 chain, which exhibits a structure expected for a neutral and yet unknown klado‐Bi10 cluster.
Bibliography:http://dx.doi.org/10.1002/anie.200703325
istex:B8A13224EFDF50FF6B75D7DE543BE941F399F6FD
DFG
ArticleID:ANIE200703325
Fonds der Chemischen Industrie
ark:/67375/WNG-2WD9WMXN-C
Institute of Nanotechnology of the Forschungszentrum Karlsruhe
This work was supported by the DFG (Center for Functional Nanostructures), the Institute of Nanotechnology of the Forschungszentrum Karlsruhe and the Fonds der Chemischen Industrie.
ObjectType-Article-1
SourceType-Scholarly Journals-1
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ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200703325