Manganese(iii)-mediated phosphinoyl radical reactions for stereoselective synthesis of phosphinoylated tetrahydronaphthalenes

• Published in: Chemical communications (Cambridge, England) Vol. 47; no. 27; pp. 7875 - 7877
• Main Authors: Pan, Xiang-Qiang, Wang, Lu, Zou, Jian-Ping, Zhang, Wei
• Format: Journal Article
• Language: English
• Published: CAMBRIDGE Royal Soc Chemistry 01.01.2011
• Subjects: chemical communication; chemical reactions; Chemistry; Chemistry, Multidisciplinary; free radicals; manganese; Physical Sciences; Science & Technology; stereoselective synthesis; tetrahydronaphthalenes; ELECTRON-SPIN-RESONANCE; LASER FLASH-PHOTOLYSIS; PHOSPHORUS-CENTERED RADICALS; TIME-RESOLVED ESR; ADDITION-REACTIONS; REACTIVITY; OXIDES; CYCLIZATION

Reactions of diphenylphosphinoyl radicals with 5-aryl-2-pentenoates or β-phenylethylene styrenes generate trans-substituted tetrahydronaphthalenes through a cascade reaction sequence.Reactions of diphenylphosphinoyl radicals with 5-aryl-2-pentenoates or β-phenylethylene styrenes generate trans-subst...