Manganese(iii)-mediated phosphinoyl radical reactions for stereoselective synthesis of phosphinoylated tetrahydronaphthalenes

Reactions of diphenylphosphinoyl radicals with 5-aryl-2-pentenoates or β-phenylethylene styrenes generate trans-substituted tetrahydronaphthalenes through a cascade reaction sequence.Reactions of diphenylphosphinoyl radicals with 5-aryl-2-pentenoates or β-phenylethylene styrenes generate trans-subst...

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Published inChemical communications (Cambridge, England) Vol. 47; no. 27; pp. 7875 - 7877
Main Authors Pan, Xiang-Qiang, Wang, Lu, Zou, Jian-Ping, Zhang, Wei
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 01.01.2011
Subjects
chemical communication
chemical reactions
Chemistry
Chemistry, Multidisciplinary
free radicals
manganese
Physical Sciences
Science & Technology
stereoselective synthesis
tetrahydronaphthalenes
ELECTRON-SPIN-RESONANCE
LASER FLASH-PHOTOLYSIS
PHOSPHORUS-CENTERED RADICALS
TIME-RESOLVED ESR
ADDITION-REACTIONS
REACTIVITY
OXIDES
CYCLIZATION
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Summary:Reactions of diphenylphosphinoyl radicals with 5-aryl-2-pentenoates or β-phenylethylene styrenes generate trans-substituted tetrahydronaphthalenes through a cascade reaction sequence.Reactions of diphenylphosphinoyl radicals with 5-aryl-2-pentenoates or β-phenylethylene styrenes generate trans-substituted tetrahydronaphthalenes through a cascade reaction sequence.
Bibliography:ObjectType-Article-1
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ISSN:1359-7345
1364-548X
1364-548X
DOI:10.1039/c1cc12343b