Facile synthesis of metal N-heterocyclic carbene complexes

A novel electrochemical procedure for the preparation of metal complexes of N-heterocyclic carbenes using imidazolium salts or corresponding silver-NHC complexes as carbene sources and electrolytes, and metal plates as the sacrificial anodes is described. The procedure is simple and good yielding wi...

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Published inChemical communications (Cambridge, England) Vol. 47; no. 10; pp. 2883 - 2885
Main Authors Liu, Bin, Zhang, Yin, Xu, Daichao, Chen, Wanzhi
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 01.01.2011
Subjects
Carbenes
Chemistry
Chemistry, Multidisciplinary
Electrochemistry
Electrolytes
Heterocyclic Compounds - chemistry
Imidazoles - chemistry
Metal plates
Methane - analogs & derivatives
Methane - chemistry
Organometallic Compounds - chemical synthesis
Organometallic Compounds - chemistry
Physical Sciences
Sacrificial anodes
Science & Technology
Synthesis
COPPER-COMPLEXES
IRON(II) COMPLEXES
LIGANDS
NICKEL
VERSATILE
RING
BEARING
CATALYTIC-ACTIVITY
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Summary:A novel electrochemical procedure for the preparation of metal complexes of N-heterocyclic carbenes using imidazolium salts or corresponding silver-NHC complexes as carbene sources and electrolytes, and metal plates as the sacrificial anodes is described. The procedure is simple and good yielding without the use of expensive or air-sensitive reagents.
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ISSN:1359-7345
1364-548X
DOI:10.1039/c0cc05260d