Surface modification by sulfated zirconia on high-capacity nickel-based cathode materials for Li-ion batteries

• Published in: Electrochimica acta Vol. 153; pp. 115 - 121
• Main Authors: Woo, Sang-Gil, Han, Jae-Hee, Kim, Ki Jae, Kim, Jae-Hun, Yu, Ji-Sang, Kim, Young-Jun
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 20.01.2015
• Subjects: cathode; Cathodes; Coating; Contact; Electrodes; High temperature; lithium secondary battery; Lithium-ion batteries; Ni-rich oxide; Nickel; Solid electrolytes; Sulfated zirconia; surface modification; Zirconium dioxide; lithium secondary battery; Ni-rich oxide; cathode; surface modification; Sulfated zirconia
• ISSN: 0013-4686; 1873-3859
• DOI: 10.1016/j.electacta.2014.12.001

•Sulfated zirconia is successfully synthesized and uniformly coated onto a nickel-rich layered lithium oxide.•The electrochemical properties of the sulfated-zirconia-coated LiNi0.8Co0.1Mn0.1O2 electrode are greatly improved.•Sulfated zirconia coating is effective in reducing side reactions between the active materials and electrolyte.•Sulfated zirconia coating contributes to forming a more stable solid electrolyte interphase layer on the cathode surface. Sulfated zirconia was successfully synthesized and uniformly coated onto a nickel-rich layered lithium oxide (LiNi0.8Co0.1Mn0.1O2), and investigated with a view to its potential use as a cathode material in Li-ion batteries. The uniformity of this sulfated zirconia coating was confirmed through electron microscopy, energy dispersive spectroscopy and Fourier transform infrared spectroscopy. Furthermore, the electrochemical properties of the sulfated-zirconia-coated LiNi0.8Co0.1Mn0.1O2 electrode were found to be greatly improved compared to those of pristine LiNi0.8Co0.1Mn0.1O2 and zirconia-coated LiNi0.8Co0.1Mn0.1O2, especially at elevated temperature (60°C). These results are directly attributed to the sulfated zirconia coating, which is effective in reducing side reactions by preventing direct contact between the active materials and electrolyte solutions, as well as forming a more stable solid electrolyte interphase (SEI) layer on the active material surface.