Single-crystal-to-single-crystal transformations and selective adsorption of porous copper(II) frameworks

A unique 4-fold interpenetrated (10,3)-b copper(II) framework exhibits reversible dehydration and rehydration in a single-crystal-to-single-crystal (SC-SC) process, and the dehydrated material can encapsulate CH(3)OH molecules, again in a SC-SC fashion, and shows selective adsorption of H(2) and CO(...

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Published inChemical communications (Cambridge, England) Vol. 47; no. 13; pp. 3787 - 3789
Main Authors Chen, Man-Sheng, Chen, Min, Takamizawa, Satoshi, Okamura, Taka-aki, Fan, Jian, Sun, Wei-Yin
Format Journal Article
LanguageEnglish
Published England 01.01.2011
Subjects
ADSORPTION
CARBON DIOXIDE
Carbon Dioxide - isolation & purification
Copper - chemistry
Crystallization
Dehydration
ENCAPSULATION
Hydrogen - isolation & purification
Materials selection
Models, Molecular
Nitrogen - isolation & purification
PHASE TRANSFORMATIONS
POROSITY
Selective adsorption
Single crystals
Transformations
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Summary:A unique 4-fold interpenetrated (10,3)-b copper(II) framework exhibits reversible dehydration and rehydration in a single-crystal-to-single-crystal (SC-SC) process, and the dehydrated material can encapsulate CH(3)OH molecules, again in a SC-SC fashion, and shows selective adsorption of H(2) and CO(2) over N(2).
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
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ISSN:1359-7345
1364-548X
DOI:10.1039/c0cc04689b