In situ generation of radical initiators using amine-borane complexes for carbohalogenation of alkenes
Atom transfer radical addition of alkyl halides to alkenes was developed using a low amount of a stable initiator, amine borane complexes. Thanks to a slow hydroboration step, the overall carbohalogenation process leads to good isolated yields.
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Published in | Chemical communications (Cambridge, England) Vol. 58; no. 13; pp. 2124 - 2127 |
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Main Authors | , , , , , |
Format | Journal Article |
Language | English |
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England
Royal Society of Chemistry
10.02.2022
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Abstract | Atom transfer radical addition of alkyl halides to alkenes was developed using a low amount of a stable initiator, amine borane complexes. Thanks to a slow hydroboration step, the overall carbohalogenation process leads to good isolated yields. |
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AbstractList | Atom transfer radical addition of alkyl halides to alkenes was developed using a low amount of a stable initiator, amine borane complexes. Thanks to a slow hydroboration step, the overall carbohalogenation process leads to good isolated yields. |
Author | Liautard, Virginie Chabaud, Laurent Pucheault, Mathieu Michaud, Guillaume Delgado, Marine Colin, Boris |
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Cites_doi | 10.1126/science.102.2640.128.a 10.1039/b714578k 10.1021/cr9400626 10.1002/adsc.202000630 10.1016/j.tetlet.2015.05.094 10.1021/ja00790a015 10.1039/P19930000891 10.1021/jo010652l 10.1021/ja00242a068 10.1002/anie.201406450 10.1021/jo0002745 10.1039/C9CC01988J 10.1021/ja01501a029 10.1055/s-1998-1985 10.1021/jo980362d 10.1039/a804291h 10.1002/adsc.202001000 10.1246/bcsj.75.853 10.1246/bcsj.62.143 10.1021/cr010001p 10.1021/jo0498720 10.1021/acs.orglett.0c03030 10.1021/ja01225a517 10.1016/B978-0-08-097742-3.00418-3 10.1021/ja0014281 10.1021/acs.joc.0c01135 10.1016/S0040-4039(00)76646-9 10.1021/ar50089a004 10.1016/S0040-4039(00)77265-0 10.1016/S0040-4039(00)60034-5 10.1021/jo981774p 10.1016/j.ica.2011.10.016 10.1021/ja0774663 10.1021/jo01226a011 10.1021/acscatal.0c02984 10.1021/ja300798k 10.1016/S0040-4039(00)77027-4 10.1039/P29890000539 10.1021/ja00206a016 10.1016/S0040-4039(00)99189-5 10.2174/138527206775192915 |
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SubjectTerms | Alkenes Boranes Chemical Sciences Halides Hydroboration Initiators Organic chemistry |
Title | In situ generation of radical initiators using amine-borane complexes for carbohalogenation of alkenes |
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