In situ generation of radical initiators using amine-borane complexes for carbohalogenation of alkenes

Atom transfer radical addition of alkyl halides to alkenes was developed using a low amount of a stable initiator, amine borane complexes. Thanks to a slow hydroboration step, the overall carbohalogenation process leads to good isolated yields.

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Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 58; no. 13; pp. 2124 - 2127
Main Authors Liautard, Virginie, Delgado, Marine, Colin, Boris, Chabaud, Laurent, Michaud, Guillaume, Pucheault, Mathieu
Format Journal Article
LanguageEnglish
Published England Royal Society of Chemistry 10.02.2022
Subjects
Alkenes
Boranes
Chemical Sciences
Halides
Hydroboration
Initiators
Organic chemistry
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Summary:Atom transfer radical addition of alkyl halides to alkenes was developed using a low amount of a stable initiator, amine borane complexes. Thanks to a slow hydroboration step, the overall carbohalogenation process leads to good isolated yields.
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ISSN:1359-7345
1364-548X
DOI:10.1039/d1cc06390a