Linear chain aluminium(III) carboxymethylphosphonate with encapsulated ammonium ions

An aluminium carboxymethylphosphonate of composition (NH(4))(2)Al(H(1/2)O(3)PCH(2)CO(2))(2) has been prepared hydrothermally. The aluminium cation is chelated by six membered rings formed from bonding by both the carboxylate and phosphonate oxygens. These chelate rings in turn form larger eight memb...

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Published inDalton transactions : an international journal of inorganic chemistry Vol. 40; no. 47; pp. 12648 - 12650
Main Authors Ayi, Ayi Anyama, Kinnibrugh, Tiffany L, Clearfield, Abraham
Format Journal Article
LanguageEnglish
Published England 01.01.2011
Subjects
Aluminium
Aluminum
Bonding
Chains
Chelating
Encapsulation
Joining
Running
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Summary:An aluminium carboxymethylphosphonate of composition (NH(4))(2)Al(H(1/2)O(3)PCH(2)CO(2))(2) has been prepared hydrothermally. The aluminium cation is chelated by six membered rings formed from bonding by both the carboxylate and phosphonate oxygens. These chelate rings in turn form larger eight membered rings by connecting to similar chelate groups to form chains running along the a-axis.
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ISSN:1477-9226
1477-9234
DOI:10.1039/c1dt11620g