Ionic liquid mediated routes to polydentate oxygen-donor adducts of cerium(III) bromide

The preparation of a series of CeBr(3) molecular adducts supported by the polydentate oxygen donor ligands diglyme, dimethoxyethane and tetraglyme is reported. The new complexes are characterized structurally by X-ray diffraction and optically by photoluminescence studies.

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Bibliographic Details
Published inDalton transactions : an international journal of inorganic chemistry Vol. 41; no. 7; pp. 1924 - 1927
Main Authors Vasudevan, Kalyan V, Smith, Nickolaus A, Scott, Brian L, Bennett, Bryan L, Muenchausen, Ross E, Gordon, John C
Format Journal Article
LanguageEnglish
Published England 01.01.2012
Subjects
Adducts
Bromides
Diffraction
Ionic liquids
Ligands
Photoluminescence
X-rays
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Summary:The preparation of a series of CeBr(3) molecular adducts supported by the polydentate oxygen donor ligands diglyme, dimethoxyethane and tetraglyme is reported. The new complexes are characterized structurally by X-ray diffraction and optically by photoluminescence studies.
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ISSN:1477-9226
1477-9234
DOI:10.1039/c2dt12333a