Solution-combustion synthesized nickel-substituted spinel cathode materials (LiNixMn2-xO4; 0≤x≤0.2) for lithium ion battery: enhancing energy storage, capacity retention, and lithium ion transport

• Published in: Electrochimica acta Vol. 128; pp. 172 - 177
• Main Authors: Kebede, Mesfin A., Kunjuzwa, Nikiwe, Jafta, Charl J., Mathe, Mkhulu K., Ozoemena, Kenneth I.
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 10.05.2014
• Subjects: Capacity retention; Cathodes; Diffraction; Energy storage; Ion transport; LiNixMn2-xO4; Lithium; Lithium batteries; lithium ion battery; Lithium ion diffusion; Nickel; Solution-combustion method; Spinel; Capacity retention; Lithium ion diffusion; LiNixMn2-xO4; lithium ion battery; Solution-combustion method
• ISSN: 0013-4686; 1873-3859
• DOI: 10.1016/j.electacta.2013.11.080

•Spherical LiNixMn2-xO4 (x=0, 0.1, 0.2) cathodes synthesized using solution combustion methods.•Low amount of nickel enhanced the cell potential and improved the capacity retention (ca. 99%).•Ni substitution minimized the Jahn-Teller effects of the LMO and enhanced lithium ion transport.•Ni substitution improved the lithium ion intercalation/de-intercalation resistance of LMO. Spherically shaped Ni-substituted LiNixMn2-xO4 (x=0, 0.1, 0.2) spinel cathode materials for lithium ion battery with high first cycle discharge capacity and remarkable cycling performance were synthesized using the solution-combustion technique. XRD confirmed the successful synthesis of the various spinel structures, with the Bragg diffraction peaks shifting to higher 2θ angles accompanied with lattice shrinking as the Ni concentration increased. The SEM images of the spinels revealed essentially spherical morphology. Galvanostatic charge-discharge experiments showed that by substituting the pristine spinel with a low amount of nickel enhanced the cell potential (hence the energy storage capability) and greatly improved the capacity retention (ca. 99%) even after 100 cycles. Electrochemical impedance spectroscopy experiments corroborated the enhanced capacity retention as lithium ion intercalation/de-intercalation resistance for the Ni substituted spinels was significantly improved (more than a magnitude higher) compared to the pristine spinel.