Hopping and Ionic Conduction in Tin Oxide-Based Thick-Film Resistor Compositions
Conduction mechanisms in tin oxide‐based thick‐film resistors have been investigated using impedance spectroscopic measurements. The sheet resistance, obtained by analyzing these impedance spectra, exhibits two regions of temperature dependence. The behavior in region I (room temperature to } 200°C)...
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| Published in | Journal of the American Ceramic Society Vol. 80; no. 5; pp. 1198 - 1202 |
|---|---|
| Main Authors | , , |
| Format | Journal Article |
| Language | English |
| Published |
Westerville, Ohio
American Ceramics Society
01.05.1997
Blackwell |
| Subjects | |
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| Abstract | Conduction mechanisms in tin oxide‐based thick‐film resistors have been investigated using impedance spectroscopic measurements. The sheet resistance, obtained by analyzing these impedance spectra, exhibits two regions of temperature dependence. The behavior in region I (room temperature to } 200°C) can be explained satisfactorily in terms of variable‐range hopping conduction and in region II (200° to }350C) by a diffusion model. It is assumed that ionic tin dissolved in glass serves as the hopping sites in region I. At higher temperatures, these tin ions may participate in an ion‐exchange‐type diffusion that results in region II behavior. |
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| AbstractList | Conduction mechanisms in tin oxide‐based thick‐film resistors have been investigated using impedance spectroscopic measurements. The sheet resistance, obtained by analyzing these impedance spectra, exhibits two regions of temperature dependence. The behavior in region I (room temperature to } 200°C) can be explained satisfactorily in terms of variable‐range hopping conduction and in region II (200° to }350C) by a diffusion model. It is assumed that ionic tin dissolved in glass serves as the hopping sites in region I. At higher temperatures, these tin ions may participate in an ion‐exchange‐type diffusion that results in region II behavior. |
| Author | Rahman, K. M. Anisur Schneider, Susan C. Seitz, Martin A. |
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| Cites_doi | 10.1080/00018738700101971 10.1016/0022-3093(80)90195-7 10.1007/BF00551732 10.1080/14786437008221061 10.1103/PhysRevB.9.2623 10.1080/14786437708232978 10.1016/0022-3093(80)90096-4 10.1103/PhysRevB.11.738 10.1080/14786437708238517 10.1007/978-3-662-02403-4 |
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| Keywords | Ionic conduction Thick film resistor Electrical properties Tin oxide Sheet resistance Tin ion Temperature effect Resistor Electrical impedance |
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| Notes | istex:CA71DF80D83C8F3307C2E39A405176891118FF8A ark:/67375/WNG-RBPGNCBX-S ArticleID:JACE1198 T. O. Mason—contributing editor Based in part on the thesis submitted by K. M. Anisur Rahman for the Ph.D. degree in Electrical and Computer Engineering, Marquette University, Milwaukee, WI, 1994. Member, American Ceramic Society. Presented in part at the 97th Annual Meeting of the American Ceramic Society, Cincinnati, OH, May 1, 1995 (Electronics and Glass Division, Paper No. SXXII–5–95). |
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| References_xml | – year: 1984 – volume: 36 start-page: 135 issue: 2 year: 1987 end-page: 18 article-title: AC Conduction in Amorphous Chalcogenide and Pnictide Semiconductors publication-title: Adv. Phys. – volume: 8 start-page: 164 issue: 4 year: 1967 end-page: 68 article-title: The Crystallisation and Decomposition of SnO–SiO Glasses publication-title: Phys. Chem. Glasses – volume: 41 start-page: 99 year: 1980 end-page: 103 article-title: Diffusion of Tin in Soda–Lime Glass between the Transformation Point and Softening Point publication-title: J. Non-Cryst. Solids – year: 1987 – year: 1988 – volume: Vol. III year: 1975 – volume: 22 start-page: 903 year: 1970 end-page: 22 article-title: Conduction in Non‐Crystalline Systems: V. Conductivity, Optical Absorption and Photoconductivity in Amorphous Semiconductors publication-title: Philos. Mag. – volume: 35 start-page: 1557 year: 1977 end-page: 75 article-title: Localized Gap States in Amorphous Semiconducting Compounds publication-title: Philos. Mag. – year: 1973 – start-page: 388 year: 1976 end-page: 94 – volume: 11 start-page: 738 year: 1975 article-title: Electron Transport and Superconductivity in Amorphous Sb and Its Alloys publication-title: Phys. Rev. B: Solid State – volume: 36 start-page: 1291 issue: 6 year: 1977 end-page: 304 article-title: A Theory of ac Conduction in Chalcogenide Glasses publication-title: Philos. Mag. – volume: 9 start-page: 2623 year: 1974 end-page: 26 article-title: Hopping Conductivity in Amorphous Antimony publication-title: Phys. Rev. B: Solid State – volume: 24 start-page: 79 issue: 4 year: 1983 end-page: 82 article-title: Diffusion of Sn(IV) in Soda–Lime Glass publication-title: Phys. Chem. Glasses – year: 1994 – volume: 40 start-page: 93 year: 1980 end-page: 118 article-title: Fast Ion Transport in Oxide Glasses publication-title: J. Non-Cryst. Solids – start-page: 1 year: 1987 end-page: 20 – volume: 15 start-page: 670 year: 1980 end-page: 76 article-title: Diffusion of Tin(IV) in Silicate Glazes and Glasses publication-title: J. Mater. Sci. – ident: e_1_2_1_13_2 doi: 10.1080/00018738700101971 – ident: e_1_2_1_18_2 doi: 10.1016/0022-3093(80)90195-7 – volume-title: An Introduction to Solid State Diffusion year: 1988 ident: e_1_2_1_15_2 contributor: fullname: Borg R. J. – volume: 8 start-page: 164 issue: 4 year: 1967 ident: e_1_2_1_7_2 article-title: The Crystallisation and Decomposition of SnO–SiO2 Glasses publication-title: Phys. Chem. Glasses contributor: fullname: Nover J. Carbo – ident: e_1_2_1_20_2 doi: 10.1007/BF00551732 – volume-title: Conduction in Non‐Crystalline Materials year: 1987 ident: e_1_2_1_5_2 contributor: fullname: Mott N. F. – ident: e_1_2_1_8_2 doi: 10.1080/14786437008221061 – start-page: 1 volume-title: Impedance Spectroscopy Emphasizing Solid Materials and Systems year: 1987 ident: e_1_2_1_3_2 contributor: fullname: Macdonald J. R. – ident: e_1_2_1_10_2 doi: 10.1103/PhysRevB.9.2623 – ident: e_1_2_1_12_2 doi: 10.1080/14786437708232978 – volume: 24 start-page: 79 issue: 4 year: 1983 ident: e_1_2_1_19_2 article-title: Diffusion of Sn(IV) in Soda–Lime Glass publication-title: Phys. Chem. Glasses contributor: fullname: Sanyal A. S. – ident: e_1_2_1_16_2 doi: 10.1016/0022-3093(80)90096-4 – volume-title: Glass Science year: 1973 ident: e_1_2_1_17_2 contributor: fullname: Doremus R. H. – start-page: 388 volume-title: Introduction to Solid State Physics year: 1976 ident: e_1_2_1_4_2 contributor: fullname: Kittel C. – ident: e_1_2_1_11_2 doi: 10.1103/PhysRevB.11.738 – ident: e_1_2_1_14_2 doi: 10.1080/14786437708238517 – ident: e_1_2_1_2_2 – ident: e_1_2_1_9_2 doi: 10.1007/978-3-662-02403-4 – volume-title: Phase Diagrams for Ceramists year: 1975 ident: e_1_2_1_6_2 contributor: fullname: Levin E. M. |
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| SubjectTerms | Applied sciences Electronic equipment and fabrication. Passive components, printed wiring boards, connectics Electronics Exact sciences and technology |
| Title | Hopping and Ionic Conduction in Tin Oxide-Based Thick-Film Resistor Compositions |
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