Electrophoretic deposition of hydroxyapatite-hexagonal boron nitride composite coatings on Ti substrate

• Published in: Materials Science & Engineering C Vol. 79; pp. 343 - 353
• Main Authors: Göncü, Yapıncak, Geçgin, Merve, Bakan, Feray, Ay, Nuran
• Format: Journal Article
• Language: English
• Published: Netherlands Elsevier B.V 01.10.2017; Elsevier BV
• Subjects: Biocompatibility; Biomedical materials; Boron; Boron Compounds - chemistry; Boron nitride; Cell proliferation; Coated Materials, Biocompatible; Coating effects; Composite; Durapatite; Electron microscopy; Electrophoretic deposition; Energy transmission; Hexagonal boron nitride; Hydroxyapatite; Materials science; Materials Testing; Microscopy, Electron, Scanning; Morphology; Orthopedics; Physical characteristics; Process parameters; Protective coatings; Raman spectroscopy; Scanning electron microscopy; Spectroscopy; Structural analysis; Studies; Substrates; Surface Properties; Surgical implants; Titanium; Titanium oxide powders; Transmission electron microscopy; Titanium; Hydroxyapatite; Hexagonal boron nitride; Composite; Electrophoretic deposition
• ISSN: 0928-4931; 1873-0191
• DOI: 10.1016/j.msec.2017.05.023

In this study, commercial pure titanium samples were coated with nano hydroxyapatite-nano hexagonal boron nitride (nano HA-nano hBN) composite by electrophoretic deposition (EPD). The effect of process parameters (applied voltage, deposition time and solid concentration) on the coating morphology, thickness and the adhesion behavior were studied systematically and crack free nano hBN-nano HA composite coating production was achieved for developing bioactive coatings on titanium substrates for orthopedic applications. For the examination of structural and morphological characteristics of the coating surfaces, various complementary analysis methods were performed. For the structural characterization, XRD and Raman Spectroscopy were used while, Scanning Electron Microscopy (SEM) equipped with an energy dispersive spectrometer (EDS) and Transmission Electron Microscopy (TEM) techniques were carried out for revealing the morphological characterization. The results showed that nano HA-nano hBN were successfully deposited on Ti surface with uniform, crack-free coating by EPD. The amounts of hBN in suspension are considered to have no effect on coating thickness. By adding hBN into HA, the morphology of HA did not change and hBN has no significant effect on porous structure. These nanostructured surfaces are expected to be suitable for proliferation of cells and have high potential for bioactive materials. [Display omitted] •The EPD technique was used to investigate the production of potentially bioactive nanoHA-nanohBN composite coatings on Ti.•The effect of process parameters on the coating morphology, thickness and the adhesion behavior were investigated.•Crack free nanoHA-nanohBN composite coating was achieved on Ti substrates for orthopaedic applications.