Dihydrogen phosphate-containing dinuclear double assemblies that demonstrate phosphate reactivity to the tetrafluoroborate anion

The ligands L1 and L2 both form dinuclear assemblies with Cu( ii ) and these react with dihydrogen phosphate so that the anion is incorporated within the assembly ( e.g. [Cu 2 L 2 (H 2 PO 4 )] 3+ ). However, in the presence of tetrafluoroborate anions the phosphate undergoes reaction with the anion...

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Published inChemical communications (Cambridge, England) Vol. 54; no. 66; pp. 9159 - 9162
Main Authors Faulkner, Robert A., Patmore, Nathan J., Rice, Craig R., Slater, Christopher
Format Journal Article
LanguageEnglish
Published England Royal Society of Chemistry 14.08.2018
Subjects
Anions
Assemblies
chemical reactions
copper
ligands
phosphates
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Summary:The ligands L1 and L2 both form dinuclear assemblies with Cu( ii ) and these react with dihydrogen phosphate so that the anion is incorporated within the assembly ( e.g. [Cu 2 L 2 (H 2 PO 4 )] 3+ ). However, in the presence of tetrafluoroborate anions the phosphate undergoes reaction with the anion forming [Cu 3 ( L1 ) 3 (O 3 POBF 3 )] 3+ and [Cu 2 ( L2 ) 2 (O 2 P(OBF 3 ) 2 )] + .
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ISSN:1359-7345
1364-548X
1364-548X
DOI:10.1039/C8CC04900A