Synthesis of a distanna [2]ferrocenophane and reactivity of [2]ferrocenophanes towards elemental sulfur and selenium

Here we report the synthesis and crystal structure of a new [2]ferrocenophane [Fe(η 5-C 5H 4) 2(Sn tBu 2) 2] with a sterically demanding distannanediyl bridge. The reactivity of the title compound towards selected main group elements was examined and in addition, this reactivity pattern was establis...

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Bibliographic Details
Published inJournal of organometallic chemistry Vol. 695; no. 24; pp. 2609 - 2613
Main Authors Bera, H., Braunschweig, H., Oechsner, A., Seeler, F., Sigritz, R.
Format Journal Article
LanguageEnglish
Published LAUSANNE Elsevier B.V 15.11.2010
Elsevier
Subjects
ansa-Complexes
Boron
Chemistry
Chemistry, Inorganic & Nuclear
Chemistry, Organic
Iron
Physical Sciences
Science & Technology
Selenium
Sulfur
Tin
Tin
Boron
Iron
Selenium
ansa-Complexes
Sulfur
MOLYBDENUM
CRYSTAL-STRUCTURE
COMPLEXES
DILITHIATION
ALKYNES
BOND
DIBORATION
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Summary:Here we report the synthesis and crystal structure of a new [2]ferrocenophane [Fe(η 5-C 5H 4) 2(Sn tBu 2) 2] with a sterically demanding distannanediyl bridge. The reactivity of the title compound towards selected main group elements was examined and in addition, this reactivity pattern was established for the related diboranediyl bridged [2]ferrocenophane [Fe(η 5-C 5H 4) 2(BNMe 2) 2]. [Display omitted] Here we report the synthesis and crystal structure of a new [2]ferrocenophane [Fe(η 5-C 5H 4) 2(Sn tBu 2) 2] with a sterically demanding distannanediyl bridge. The reactivity of the title compound towards selected main group elements was examined and in addition, this reactivity pattern was established for the related diboranediyl bridged [2]ferrocenophane [Fe(η 5-C 5H 4) 2(BNMe 2) 2].
ISSN:0022-328X
1872-8561
DOI:10.1016/j.jorganchem.2010.08.028