Development of the integrated methanol fuel processor using micro-channel patterned devices and its performance for steam reforming of methanol

• Published in: International journal of hydrogen energy Vol. 32; no. 18; pp. 5103 - 5108
• Main Authors: Sohn, Jung Min, Chang Byun, Young, Yeon Cho, Jun, Choe, Jaehoon, Ho Song, Kwang
• Format: Journal Article
• Language: English
• Published: Oxford Elsevier Ltd 01.12.2007; Elsevier
• Subjects: Alternative fuels. Production and utilization; Applied sciences; Energy; Energy. Thermal use of fuels; Equipments for energy generation and conversion: thermal, electrical, mechanical energy, etc; Exact sciences and technology; Fuel cells; Fuels; Hydrogen; Methanol reforming; Microchannel reactor; Plate type fuel processor; Microchannel reactor; Hydrogen; Methanol reforming; Plate type fuel processor; Combustion; Combustion chamber; Platinum; Stainless steel; Heat exchanger; Steam reforming; Thermal efficiency; Performance; Catalyst; Fuel cell; Hydrogen production; Methanol
• ISSN: 0360-3199; 1879-3487
• DOI: 10.1016/j.ijhydene.2007.08.012

A plate-type integrated fuel processor consisting of three different micro-structured modules was developed for hydrogen production in a 150 W PEMFC system. This system includes a reformer with combustor, two heat exchangers, and an evaporator with a combustor. Methanol steam reforming was chosen as a means to produce hydrogen for the PEMFC system. This system could be operated without any external heat supply. Hydrogen was used as the initial combustion fuel during startup, while methanol was used later. Cu / Zn / Al 2 O 3 and Pt / Al 2 O 3 catalysts were chosen for the steam reforming of methanol and the combustion, respectively, and coated on microchannel-patterned stainless steel sheets. The integrated system was operated consistently with 80% of methanol conversion at 300 ∘ C for 20 h without deactivation of the catalysts. The production rate on dry basis and the composition of hydrogen was 2.4 NL min - 1 and ca 70%, respectively. Overall the thermal efficiency of this fuel processor based on the LHV was 56.7%.