Recent advances in palladium-catalyzed (hetero)annulation of CC bonds with ambiphilic organo(pseudo)halides

• Published in: Chemical communications (Cambridge, England) Vol. 57; no. 62; pp. 7610 - 7624
• Main Authors: Ni, Hui-Qi, Cooper, Phillippa, Engle, Keary M.
• Format: Journal Article
• Language: English
• Published: Cambridge Royal Society of Chemistry 03.08.2021
• Subjects: Alkenes; catalytic activity; chemical communication; Chemical reactions; couplings; Dienes; Halides; Organic chemistry; Palladium; strains; styrene; Styrenes

Palladium has proven to be effective in catalyzing the (hetero)annulation of CC bonds with ambiphilic organo(pseudo)halides. Through the employment of appropriate ambiphilic coupling partners, efficient annulation of a variety of allenes, 1,3-dienes, strained alkenes, styrenes, and other CC bond v...