Recent advances in palladium-catalyzed (hetero)annulation of CC bonds with ambiphilic organo(pseudo)halides

Palladium has proven to be effective in catalyzing the (hetero)annulation of CC bonds with ambiphilic organo(pseudo)halides. Through the employment of appropriate ambiphilic coupling partners, efficient annulation of a variety of allenes, 1,3-dienes, strained alkenes, styrenes, and other CC bond v...

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Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 57; no. 62; pp. 7610 - 7624
Main Authors Ni, Hui-Qi, Cooper, Phillippa, Engle, Keary M.
Format Journal Article
LanguageEnglish
Published Cambridge Royal Society of Chemistry 03.08.2021
Subjects
Alkenes
catalytic activity
chemical communication
Chemical reactions
couplings
Dienes
Halides
Organic chemistry
Palladium
strains
styrene
Styrenes
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Summary:Palladium has proven to be effective in catalyzing the (hetero)annulation of CC bonds with ambiphilic organo(pseudo)halides. Through the employment of appropriate ambiphilic coupling partners, efficient annulation of a variety of allenes, 1,3-dienes, strained alkenes, styrenes, and other CC bond variants can be achieved to provide direct access to numerous useful hetero- and carbocyclic scaffolds. In this Feature Article, we summarize palladium-catalyzed (hetero)annulation methods reported since 2005 (spanning just over 15 years) and discuss outstanding challenges in this area of study.
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ISSN:1359-7345
1364-548X
1364-548X
DOI:10.1039/D1CC02836G