Virtual standard for wavelength-dispersive electron-probe microanalysis

• Published in: Mikrochimica acta (1966) Vol. 161; no. 3-4; pp. 427 - 432
• Main Authors: Merlet, Claude, Llovet, Xavier, Dugne, Olivier, Brémier, Stephan, Van Renterghem, Wouter, Restani, Renato
• Format: Journal Article Conference Proceeding
• Language: English
• Published: Vienna Springer-Verlag 01.06.2008; Springer; Springer Verlag
• Subjects: Analytical Chemistry; Characterization and Evaluation of Materials; Chemistry; Chemistry and Materials Science; Engineering Sciences; Exact sciences and technology; General, instrumentation; Materials; Microengineering; Nanochemistry; Nanotechnology; Original Paper; Keywords: Actinide elements; EPMA; WDS; absolute calibration; Electron microprobe; Uncertainty; Microanalysis; WDS; absolute calibration; Instrumentation; Calibration; Proportional counter; Actinide; Actinide elements; Accuracy; Electron microprobe analysis; EPMA; actinide elements
• ISSN: 0026-3672; 1436-5073
• DOI: 10.1007/s00604-007-0856-2

. A calibration method aimed at converting X-ray intensities into absolute units has been tested in different electron microprobes. The calibration requires measurement of the X-ray peak profile and measurement and calculation of the bremsstrahlung intensity emitted from a reference sample, at the energy of the X-ray line of interest. Specifically, measurements of the U Mα and Mβ lines emitted from UO 2 and bremsstrahlung intensities emitted from an Al reference sample have been performed on five different instruments. The aim of the work is to determine to what accuracy X-ray intensities emitted from reference samples of actinide elements are transferable among different electron microprobes (virtual standard). The influence of the focussing geometry and different crystals and proportional counters used is analysed. Strategies to reduce the uncertainties affecting the absolute calibration of the studied lines are discussed.