Modular 1,1′‐Ferrocenediyl‐cored P‐Stereogenic Diphosphines: ′′JDayPhos′′ Series and its Use in Rhodium(I)‐Catalyzed Hydrogenation

A novel ferrocene‐based P‐stereogenic diphospine ligand series dubbed JDayPhos was developed, which rhodium(I) complexes of some of its members exhibited excellent enantioselectivity (up to >99% ee) and high activity in asymmetric hydrogenation of β‐unsubstituted or ‐substituted itaconates and α‐...

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Bibliographic Details
Published inAdvanced synthesis & catalysis Vol. 360; no. 13; pp. 2566 - 2570
Main Authors Poklukar, Gašper, Stephan, Michel, Mohar, Barbara
Format Journal Article
LanguageEnglish
Published WEINHEIM Wiley 04.07.2018
Wiley Subscription Services, Inc
Subjects
Asymmetric catalysis
Carboxylates
Carboxylic acids
Chemistry
Chemistry, Applied
Chemistry, Organic
Enantiomers
Hydrogenation
P-ligands
Physical Sciences
Rhodium
Science & Technology
PHOSPHORUS
ALKYLATION
SUBSTITUTED CINNAMIC-ACIDS
Carboxylic acids
Asymmetric catalysis
Hydrogenation
CATALYZED ASYMMETRIC HYDROGENATION
HIGHLY ENANTIOSELECTIVE HYDROGENATION
Rhodium
P-ligands
OLEFINS
R-SMS-PHOS
STEREOSELECTIVE-SYNTHESIS
DERIVATIVES
FERROCENYL LIGANDS
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Summary:A novel ferrocene‐based P‐stereogenic diphospine ligand series dubbed JDayPhos was developed, which rhodium(I) complexes of some of its members exhibited excellent enantioselectivity (up to >99% ee) and high activity in asymmetric hydrogenation of β‐unsubstituted or ‐substituted itaconates and α‐methylene‐γ‐oxo‐carboxylates.
ISSN:1615-4150
1615-4169
DOI:10.1002/adsc.201800255