Diazo Compounds: Versatile Synthons for the Synthesis of Nitrogen Heterocycles via Transition Metal‐Catalyzed Cascade C–H Activation/Carbene Insertion/Annulation Reactions

This review covers some unique diazo compounds, the coupling partners to access various versatile functionalized nitrogen heterocycles, such as indoles, indolines, isoquinolines, isoquinolones, and so on. Different transition metals (such as Rh, Pd, Ru, Ir, Cu, and Co) are involved in these transfor...

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Published inAdvanced synthesis & catalysis Vol. 361; no. 5; pp. 919 - 944
Main Authors Xiang, Yunyu, Wang, Cong, Ding, Qiuping, Peng, Yiyuan
Format Journal Article
LanguageEnglish
Published Heidelberg Wiley Subscription Services, Inc 05.03.2019
Subjects
Activation
carbene insertion
Cascade chemical reactions
Chemical reactions
Chemical synthesis
Coupling (molecular)
C–H activation
diazo compounds
Heterocyclic compounds
Indoles
Insertion
intramolecular annulation
nitrogen heterocycles
Organic chemistry
Palladium
Transition metals
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Summary:This review covers some unique diazo compounds, the coupling partners to access various versatile functionalized nitrogen heterocycles, such as indoles, indolines, isoquinolines, isoquinolones, and so on. Different transition metals (such as Rh, Pd, Ru, Ir, Cu, and Co) are involved in these transformations, which involve consecutive processes: transition metal‐catalyzed cascade C–H activation/carbene insertion/intramolecular annulation.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
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ISSN:1615-4150
1615-4169
DOI:10.1002/adsc.201800960