Crystalline structure, energy calculation and dehydriding thermodynamics of magnesium hydride from reactive milling

• Published in: International journal of hydrogen energy Vol. 40; no. 35; pp. 11484 - 11490
• Main Authors: Zhou, Shixue, Zhang, Qianqian, Chen, Haipeng, Zang, Xuejing, Zhou, Xinpei, Wang, Ruolin, Jiang, Xiaojing, Yang, Bo, Jiang, Ruiqian
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 21.09.2015
• Subjects: First-principles calculation; Hydrogen storage; Magnesium hydride; Surface energy; Thermodynamics; Thermodynamics; Hydrogen storage; First-principles calculation; Magnesium hydride; Surface energy
• ISSN: 0360-3199; 1879-3487
• DOI: 10.1016/j.ijhydene.2015.02.059

Magnesium hydride was prepared by reactive milling under hydrogen atmosphere using carbon from anthracite coal as milling aid, and then its crystal structure and thermal stability were investigated. The phase transition of β-MgH2 to γ-MgH2 during intensive milling is confirmed by electron diffraction, high resolution electron microscope observation and X-ray diffraction. According to first-principles calculation, the supercell based on γ-MgH2 (1 1 0) plane is the most unstable with surface energy of 1.23 J/m2 and dehydriding enthalpy change of 44.66 kJ/mol, while that of β-MgH2 (1 1 0) plane is the most stable with surface energy of 0.19 J/m2 and enthalpy change of 78.16 kJ/mol. The differential scanning calorimetric analysis shows that γ-MgH2 presents much lower hydrogen desorption temperature and heat absorption than β-MgH2. The enthalpy change determined by experimental isotherms also indicates that the material with more γ-MgH2 from longer time of milling is lower. •MgH2 with β and γ phases is prepared from Mg and H2 by reactive milling.•γ-MgH2 presents lower temperature and heat absorption for hydrogen desorption.•γ phase leaves more surface Mg–H bond broken and has more irregular atom arrangement.•γ phase has higher surface energy and lower dehydriding enthalpy change.