Nuclear Spin-lattice Relaxation in Sn(CH3)4

Nuclear magnetic relaxation T1 of solid Sn(CH3)4 increased monotonously with temperature between 77 and 217 K. The activation energy for intramolecular methyl reorientation was 2.6±0.3 kJ mol−1. From measurements on the liquid phase, the apparent activation energy associated with the relaxation proc...

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Bibliographic Details
Published inBulletin of the Chemical Society of Japan Vol. 49; no. 12; p. 3684
Main Authors Hasebe, Tooru, Soda, Gen, Chihara, Hideaki
Format Journal Article
LanguageEnglish
Published The Chemical Society of Japan 01.01.1976
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Summary:Nuclear magnetic relaxation T1 of solid Sn(CH3)4 increased monotonously with temperature between 77 and 217 K. The activation energy for intramolecular methyl reorientation was 2.6±0.3 kJ mol−1. From measurements on the liquid phase, the apparent activation energy associated with the relaxation process was 8.6 kJ mol−1. Differential thermal analyses revealed the existence of another unstable solid phase.
ISSN:0009-2673
1348-0634
DOI:10.1246/bcsj.49.3684