Glass and Liquid Chemistry of Coordination Polymers and MOFs

The chemistry of coordination polymers and metal-organic frameworks (MOFs) has progressed largely with the development of crystallography. The study of “disordered systems” such as the liquid and glassy states of coordination polymers and MOFs has been developed in recent years, and various methods...

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Bibliographic Details
Published inBulletin of the Chemical Society of Japan Vol. 96; no. 9; pp. 887 - 898
Main Author Horike, Satoshi
Format Journal Article
LanguageEnglish
Published Tokyo The Chemical Society of Japan 15.09.2023
Chemical Society of Japan
SeriesThe Chemical Society of Japan Award for Young Chemists for 2013
Subjects
Coordination polymers
Crystal structure
Crystallography
Glass
Liquid phases
Liquids
Metal-organic frameworks
Physicochemical properties
Polymers
Softness
Structural design
Synchrotron radiation
Synchrotrons
Coordination polymer/MOF
Glass
Phase transition
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Summary:The chemistry of coordination polymers and metal-organic frameworks (MOFs) has progressed largely with the development of crystallography. The study of “disordered systems” such as the liquid and glassy states of coordination polymers and MOFs has been developed in recent years, and various methods have been recognised to produce glasses from crystals. The structures of the glass and liquid phases are studied using synchrotron radiation X-rays and spectroscopy. Many of them have the coordination bond-based network structure found in the crystal structures. This suggests that the structural design principles of coordination chemistry can be applied to glasses and liquids of coordination polymers and MOFs. The inherent properties of the disordered system, such as wide compositions and high internal degrees of freedom, high material formability and softness, contribute to the coupled physicochemical properties.
Bibliography:ObjectType-Article-1
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ISSN:0009-2673
1348-0634
DOI:10.1246/bcsj.20230152