Intrinsic and extrinsic size effects in the deformation of amorphous CuZr/nanocrystalline Cu nanolaminates

• Published in: Acta materialia Vol. 80; pp. 94 - 106
• Main Authors: WEI GUO, JÄGLE, Eric, JIAHAO YAO, MAIER, Verena, KORTE-KERZEL, Sandra, SCHNEIDER, Jochen M, RAABE, Dierk
• Format: Journal Article
• Language: English
• Published: Kidlington Elsevier 01.11.2014
• Subjects: Amorphous materials; AMORPHOUS STRUCTURE; Applied sciences; Compressing; Copper; COPPER ALLOYS (40 TO 99.3 CU); CRACK GROWTH; Crack propagation; DEFORMATION; Exact sciences and technology; LAMINATES; Metallic glasses; Metals. Metallurgy; MICROSTRUCTURES; Nanocrystals; Nanostructure; SIZE EFFECT; Slip bands; SLIP PLANES; ZIRCONIUM COPPERS; Metallic glasses; Shear; Deformation; Nanolaminates; Size effect; Amorphous alloy; Nanotwins; Shear band; Nanocrystal; Metallic glass
• ISSN: 1359-6454; 1873-2453
• DOI: 10.1016/j.actamat.2014.07.027

Introducing a soft crystalline phase into an amorphous alloy can promote the compound's ductility. Here we synthesized multilayered nanolaminates consisting of alternating amorphous Cu54Zr46 and nanocrystalline Cu layers. The Cu layer thickness was systematically varied in different samples. Mechanical loading was imposed by nanoindentation and micropillar compression. Increasing the Cu layer thickness from 10 to 100nm led to a transition from sharp, cross-phase shear banding to gradual bending and co-deformation of the two layer types (amorphous/nanocrystalline). Specimens with a sequence of 100nm amorphous Cu54Zr46 and 50nm Cu layers show a compressive flow stress of 2.57 plus or minus 0.21GPa, matching the strength of pure CuZr metallic glass, hence exceeding the linear rule of mixtures. In pillar compression, 40% strain without fracture was achieved by the suppression of percolative shear band propagation. The results show that inserting a ductile nanocrystalline phase into a metallic glass prevents catastrophic shear banding. The mechanical response of such nanolaminates can be tuned by adjusting the layer thickness.