Plasticizers and Salt Concentrations Effects on Polymer Gel Electrolytes Based on Poly (Methyl Methacrylate) for Electrochemical Applications

• Published in: Gels Vol. 8; no. 6; p. 363
• Main Authors: Rizzuto, Carmen, Teeters, Dale C., Barberi, Riccardo C., Castriota, Marco
• Format: Journal Article
• Language: English
• Published: Basel MDPI AG 08.06.2022; MDPI
• Subjects: ATR-FT-IR; Cationic polymerization; Conductivity; DSC; Electrochemical analysis; Electrolytes; Fourier transforms; gel; impedance spectroscopy; Infrared spectroscopy; Ion currents; linear sweep voltammetry; Lithium; Lithium perchlorates; Monomers; Plasticizers; polymer electrolyte; Polymer gels; Polymers; Polymethyl methacrylate; Propylene; Solvents; Spectrum analysis; Stability; Thermodynamic properties; Viscosity
• ISSN: 2310-2861; 2310-2861
• DOI: 10.3390/gels8060363

This work describes the electrochemical properties of a type of PMMA-based gel polymer electrolytes (GPEs). The gel polymer electrolyte systems at a concentration of (20:80) % w/w were prepared from poly (methyl methacrylate), lithium perchlorate LiClO4 and single plasticizer propylene carbonate (PMMA-Li-PC) and a mixture of plasticizers made by propylene carbonate and ethylene carbonate in molar ratio 1:1, (PMMA-Li-PC-EC). Different salt concentrations (0.1 M, 0.5 M, 1 M, 2 M) were studied. The effect of different plasticizers (single and mixed) on the properties of gel polymer electrolytes were considered. The variation of conductivity versus salt concentration, thermal properties using DSC and TGA, anodic stability and FTIR spectroscopy were used in this study. The maximum ionic conductivity of σ = 0.031 S/cm were obtained for PMMA-Li-PC-EC with a salt concentration equal to 1 M. Ion-pairing phenomena and all ion associations were observed between lithium cations, plasticizers and host polymers through FTIR spectroscopy. The anodic stability of the PMMA-based gel polymer electrolytes was recorded up to 4 V. The glass temperatures of these electrolytes were estimated. We found they were dependent on the plasticization effect of plasticizers on the polymer chains and the increase of the salt concentration. Unexpectedly, it was determined that an unreacted PMMA monomer was present in the system, which appears to enhance ion conduction. The presence and possibly the addition of a monomer may be a technique for increasing ion conduction in other gel systems that warrants further study.