Crystal Structure of Di-μ-bromo-bis{[bis(2-nitrocinnamaldehyde)-2,2′-diiminobiphenyl-N,N′]copper(I)}

The title complex, [Cu(μ-Br)(nca2dab)]2 [nca2dab is N,N′-bis(2-nitrocinnamaldehyde)-2,2′-diiminobiphenyl], has a dimeric structure, where two copper(I) ions are doubly bridged by bromo substituents. The coordination geometry around the Cu atom is a distorted tetrahedron formed by two N atoms from a...

Full description

Saved in:
Bibliographic Details
Published inAnalytical Sciences: X-ray Structure Analysis Online Vol. 22; pp. x139 - x140
Main Authors DEHGHANPOUR, Saeed, MAHMOUDI, Ali, HADJIKHANI, Ramin, MOJAHED, Fresia, BIJANZADEH, Hamid Reza
Format Journal Article
LanguageEnglish
Published The Japan Society for Analytical Chemistry 2006
Online AccessGet full text

Cover

More Information
Summary:The title complex, [Cu(μ-Br)(nca2dab)]2 [nca2dab is N,N′-bis(2-nitrocinnamaldehyde)-2,2′-diiminobiphenyl], has a dimeric structure, where two copper(I) ions are doubly bridged by bromo substituents. The coordination geometry around the Cu atom is a distorted tetrahedron formed by two N atoms from a bidentate nca2dab ligand and two bromo substituents. The distance between the two Cu atoms is 2.6650(8)Å. The nca2dab ligand adopts a Z,Z configuration.
ISSN:1348-2238
1348-2238
DOI:10.2116/analscix.22.x139