Mononuclear boron(III) complexes of neo bidentate thioimines derived from hydrazinecarbodithioic acid

• Published in: Applied organometallic chemistry Vol. 13; no. 3; pp. 175 - 182
• Main Authors: Singh, R. V., Gupta, Neeti, Saxena, Seema, Saxena, Chitra
• Format: Journal Article
• Language: English
• Published: Chichester, UK John Wiley & Sons, Ltd 01.03.1999; Wiley
• Subjects: Antibacterial agents; Antibiotics. Antiinfectious agents. Antiparasitic agents; antimicrobial screening; B derivatives; bajra plant; Biological and medical sciences; Chemical control; Chemistry; Control; Exact sciences and technology; Fundamental and applied biological sciences. Psychology; Fungal plant pathogens; Medical sciences; Organic chemistry; organoboron(III) complexes; Organometalloidal and organometallic compounds; Pharmacology. Drug treatments; Phytopathology. Animal pests. Plant and forest protection; Preparations and properties; spectroscopic studies; Pseudomonadales; Monocotyledones; Alternaria brassicicola; Escherichia coli; Furan derivatives; Pennisetum glaucum; Cereal crop; Pyridine derivatives; Fungi; Thiophene derivatives; Structure activity relation; Gramineae; Pseudomonas syringae pv. phaseolicola; Angiospermae; Bacteria; Micrococcales; Pseudomonadaceae; Micrococcaceae; Fungi Imperfecti; Chemical synthesis; Staphylococcus aureus; Enterobacteriaceae; Thallophyta; Fusarium oxysporum; Pesticides; Benzene derivatives; Organic ligand; In vitro; Fungicide; Organic dithiocarbazate; In vivo; Xanthomonas campestris; Hydroxo complex; Boron Organic compounds; Spermatophyta; Macrophomina phaseolina; Boron III Complexes; Antibacterial agent
• ISSN: 0268-2605; 1099-0739
• DOI: 10.1002/(SICI)1099-0739(199903)13:3<175::AID-AOC823>3.0.CO;2-7

Boron chemistry has been intensively studied in the recent past. Although the study of the interactions between transition‐metal ions and the phenyl methylene ester derivatives of hydrazine carbodithioic acids has been carried out on a long period, particularly via the formation of adducts, their interaction of Main Group metal ions and the formation of their coordination complexes are subjects of current interest. We have synthesized and isolated a variety of complexes of phenyl dihydroxyborane with substituted dithiocarbazates. The benzene‐soluble, high‐molecular‐weight complexes have been characterized using a wide range of analytical and spectroscopic techniques. The pathogenicity of microbial infections associated with the complexes have been subjected to a variety of biointeraction studies and the results are discussed. Copyright © 1999 John Wiley & Sons, Ltd.