Influence of electrochemical properties on electrochemical migration of SnPb and SnBi solders

SnPb solders have been widely used in many fields because of their excellent solderability. To respond to environmental and health concerns regarding SnPb solders, it is necessary to develop lead-free solder for electronic assembly. In this paper, the resistance to the electrochemical migration of e...

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Published inMetals and materials international Vol. 16; no. 5; pp. 739 - 745
Main Authors Yoo, Y. R., Kim, Y. S.
Format Journal Article
LanguageEnglish
Published Springer The Korean Institute of Metals and Materials 01.10.2010
Springer Nature B.V
대한금속·재료학회
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ISSN1598-9623
2005-4149
DOI10.1007/s12540-010-1007-6

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Abstract SnPb solders have been widely used in many fields because of their excellent solderability. To respond to environmental and health concerns regarding SnPb solders, it is necessary to develop lead-free solder for electronic assembly. In this paper, the resistance to the electrochemical migration of eutectic SnPb and SnBi solder alloys was evaluated and analyzed to detect the difference in the electrochemical migration behavior between these solders by their electrochemical properties. Pb and Bi additions to a Sn-base solder improved the resistance to electrochemical migration because of enhanced polarization properties. The resistance was closely related to the cathodic deposition efficiency and the anodic dissolution behavior. In addition, the composition of the dendrite formed by the electrochemical migration was related to the standard electrode potential of the alloying element.
AbstractList SnPb solders have been widely used in many fields because of their excellent solderability. To respond to environmental and health concerns regarding SnPb solders, it is necessary to develop lead-free solder for electronic assembly. In this paper, the resistance to the electrochemical migration of eutectic SnPb and SnBi solder alloys was evaluated and analyzed to detect the difference in the electrochemical migration behavior between these solders by their electrochemical properties. Pb and Bi additions to a Sn-base solder improved the resistance to electrochemical migration because of enhanced polarization properties. The resistance was closely related to the cathodic deposition efficiency and the anodic dissolution behavior. In addition, the composition of the dendrite formed by the electrochemical migration was related to the standard electrode potential of the alloying element.
SnPb solders have been widely used in many fields because of their excellent solderability. To respond to environmental and health concerns regarding SnPb solders, it is necessary to develop lead-free solder for electronic assembly. In this paper, the resistance to the electrochemical migration of eutectic SnPb and SnBi solder alloys was evaluated and analyzed to detect the difference in the electrochemical migration behavior between these solders by their electrochemical properties. Pb and Bi additions to a Sn-base solder improved the resistance to electrochemical migration because of enhanced polarization properties. The resistance was closely related to the cathodic deposition efficiency and the anodic dissolution behavior. In addition, the composition of the dendrite formed by the electrochemical migration was related to the standard electrode potential of the alloying element. KCI Citation Count: 14
Author Yoo, Y. R.
Kim, Y. S.
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  fullname: Kim, Y. S.
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  organization: Materials Research Center for Energy and Green Technology, School of Advanced Materials Engineering, Andong National University
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SubjectTerms Alloys
Characterization and Evaluation of Materials
Chemistry and Materials Science
Dendritic structure
Deposition
Engineering Thermodynamics
Eutectics
Heat and Mass Transfer
Lead (metal)
Machines
Magnetic Materials
Magnetism
Manufacturing
Materials Science
Metallic Materials
Migration
Processes
Solders
Solid Mechanics
재료공학
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Title Influence of electrochemical properties on electrochemical migration of SnPb and SnBi solders
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