Thiazolium salt-catalyzed C-C triple bond cleavage for accessing substituted 1-naphthols via benzannulation
The first thiazolium salt-catalyzed C-C triple bond cleavage of benzene-linked allene-ynes has been established. The reaction pathway involves [2+2] cycloaddition and ring-opening of in situ generated cyclobutenes with H2O under mild and convenient conditions, and provides practical access to substi...
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Published in | Chemical communications (Cambridge, England) Vol. 54; no. 2; pp. 164 - 167 |
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Main Authors | , , , , , , |
Format | Journal Article |
Language | English |
Published |
CAMBRIDGE
Royal Soc Chemistry
01.01.2018
Royal Society of Chemistry |
Subjects | |
Online Access | Get full text |
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Summary: | The first thiazolium salt-catalyzed C-C triple bond cleavage of benzene-linked allene-ynes has been established. The reaction pathway involves [2+2] cycloaddition and ring-opening of in situ generated cyclobutenes with H2O under mild and convenient conditions, and provides practical access to substituted 1-naphthols with potentially valuable applications. |
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Bibliography: | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
ISSN: | 1359-7345 1364-548X |
DOI: | 10.1039/c7cc08792f |