Highly active iridium(I) complexes for catalytic hydrogen isotope exchange

Practically convenient methods have been developed for the preparation of new iridium complexes, possessing bulky N-heterocyclic carbene and phosphine ligands; these routinely handled complexes are highly active catalysts within directed hydrogen isotope exchange processes.

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Bibliographic Details
Published inChemical communications (Cambridge, England) no. 9; pp. 1115 - 1117
Main Authors Brown, Jack A., Irvine, Stephanie, Kennedy, Alan R., Kerr, William J., Andersson, Shalini, Nilsson, Goeran N.
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 01.01.2008
Subjects
Catalysis
Chemistry
Chemistry, Multidisciplinary
Deuterium - chemistry
Heterocyclic Compounds - chemistry
Hydrocarbons - chemistry
Hydrogen - chemistry
Iridium - chemistry
Isotope Labeling
Ligands
Magnetic Resonance Spectroscopy - methods
Methane - analogs & derivatives
Methane - chemistry
Models, Molecular
Molecular Structure
Organometallic Compounds - chemical synthesis
Organometallic Compounds - chemistry
Phosphines - chemistry
Physical Sciences
Science & Technology
ACTIVATION
DEUTERATION
ACIDS
DEUTERIUM-EXCHANGE
N-HETEROCYCLIC CARBENES
LIGAND
RHODIUM TRICHLORIDE
AROMATIC-COMPOUNDS
C-H
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Summary:Practically convenient methods have been developed for the preparation of new iridium complexes, possessing bulky N-heterocyclic carbene and phosphine ligands; these routinely handled complexes are highly active catalysts within directed hydrogen isotope exchange processes.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
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ISSN:1359-7345
1364-548X
DOI:10.1039/b715938b