A neptunium( v )-mediated interwoven transuranium-rotaxane network incorporating a mechanically interlocked [ c 2]daisy chain unit

As an extension of actinide-rotaxane complexes from uranium to transuranium, we report the first crystal structure of a neptunium-rotaxane complex, NRCP-1, in which an interwoven neptunium( v )-rotaxane coordination network incorporating a mechanically-interlocked [ c 2]daisy chain unit is promoted...

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Published inChemical communications (Cambridge, England) Vol. 54; no. 62; pp. 8645 - 8648
Main Authors Mei, Lei, Xu, Chao, Wu, Qun-yan, Hu, Kong-qiu, Yuan, Li-yong, Chen, Jing, Xiao, Cheng-liang, Wang, Shu-ao, Chai, Zhi-fang, Shi, Wei-qun
Format Journal Article
LanguageEnglish
Published England Royal Society of Chemistry 2018
Subjects
Chains
chemical reactions
Crystal structure
macrocyclic compounds
Neptunium
Shafts (machine elements)
Uranium
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Summary:As an extension of actinide-rotaxane complexes from uranium to transuranium, we report the first crystal structure of a neptunium-rotaxane complex, NRCP-1, in which an interwoven neptunium( v )-rotaxane coordination network incorporating a mechanically-interlocked [ c 2]daisy chain unit is promoted via the simultaneous coordination of cucurbituril (CB6) and axle molecules in [2]pseudorotaxane to Np V .
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ISSN:1359-7345
1364-548X
1364-548X
DOI:10.1039/C8CC05122D