Chiral separation and characterization of triazatruxene-based face-rotating polyhedra: the role of non-covalent facial interactions

We constructed a series of novel chiral molecular face-rotating polyhedra (FRP) from two 10,15-dihydro-5H-diindolo[3,2-a:3',2'-c]carbazole (triazatruxene) derivatives and trans-1,2-cyclohexane diamine, and investigated how facial interactions and the positions of substituents determine the...

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Published inChemical communications (Cambridge, England) Vol. 54; no. 37; pp. 4685 - 4688
Main Authors Zhang, Pei, Wang, Xinchang, Xuan, Wei, Peng, Pixian, Li, Zhihao, Lu, Ruqiang, Wu, Shuang, Tian, Zhongqun, Cao, Xiaoyu
Format Journal Article
LanguageEnglish
Published England Royal Society of Chemistry 2018
Subjects
Chirality
Cyclohexane
Molecular chains
Polyhedra
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Summary:We constructed a series of novel chiral molecular face-rotating polyhedra (FRP) from two 10,15-dihydro-5H-diindolo[3,2-a:3',2'-c]carbazole (triazatruxene) derivatives and trans-1,2-cyclohexane diamine, and investigated how facial interactions and the positions of substituents determine the diastereoselectivity and geometry of the final assemblies.
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ISSN:1359-7345
1364-548X
DOI:10.1039/c8cc02049c