Evolution of reactive unsaturated interfacial modifiers for polyolefin based composites
The development of a novel reactive unsaturated interfacial modifier for filled (magnesium hydroxide, aluminium hydroxide and calcium carbonate) polyolefins is reviewed. Initial work explored maleimide functional candidate molecules including 1,3-phenylene dimaleimide (1,3-PDM) and a range of linear...
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Published in | Composite interfaces Vol. 13; no. 8-9; pp. 717 - 736 |
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Main Authors | , , , , , , , |
Format | Journal Article |
Language | English |
Published |
Taylor & Francis Group
01.01.2006
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Subjects | |
Online Access | Get full text |
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Summary: | The development of a novel reactive unsaturated interfacial modifier for filled (magnesium hydroxide, aluminium hydroxide and calcium carbonate) polyolefins is reviewed. Initial work explored maleimide functional candidate molecules including 1,3-phenylene dimaleimide (1,3-PDM) and a range of linear alkyl dimaleimides. Most of the dimaleimides were very effective interfacial modifiers in polypropylene and poly(ethylene-co-vinylacetate) (18% w/w vinylacetate) based composites. However, the dimaleimides caused the composites to have a distinct pink/brown colouration apart from when the maleimide groups were spaced by a C12 alkyl chain. The problem with colour and high effective dosage prompted a switch to unsaturated carboxylic acid based systems. The performance of a range of unsaturated carboxylic acids and the hexafunctional monomer trimethylolpropane triacrylate are reviewed, together with a novel oligomeric unsaturated carboxylic acid (OUCA) based system developed by the Noveon Division of Lubrizol Limited. The data obtained from this series of interfacial modifiers, and adsorption studies on 1,3-PDM and OUCA, afforded some insight into the competing factors (such as the strength of adsorption versus ability to form a polymerised interfacial layer and the ability to react with matrix chains) that significantly affect the coupling performance of interfacial modifiers. |
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Bibliography: | ObjectType-Article-2 SourceType-Scholarly Journals-1 ObjectType-Feature-1 content type line 23 |
ISSN: | 0927-6440 1568-5543 |
DOI: | 10.1163/156855406779366750 |