The dark side of photocatalysis: near-infrared photoredox catalysis for organic synthesis

Photoredox catalysis is now considered as a major topic in the field of organic synthesis. Recently, important progress has been made in the development of new processes involving low-energy wavelengths: Near-Infrared (NIR) photoredox catalysis. Shifting from visible to NIR light brings many advanta...

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Published inOrganic chemistry frontiers an international journal of organic chemistry Vol. 8; no. 23; pp. 6783 - 6790
Main Authors Sellet, Nicolas, Cormier, Morgan, Goddard, Jean-Philippe
Format Journal Article
LanguageEnglish
Published London Royal Society of Chemistry 23.11.2021
Subjects
Catalysis
Chemical bonds
Chemical Sciences
Chemical synthesis
I.R. radiation
Material chemistry
Near infrared radiation
Organic chemistry
Photocatalysis
Photoredox catalysis
Wavelengths
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Summary:Photoredox catalysis is now considered as a major topic in the field of organic synthesis. Recently, important progress has been made in the development of new processes involving low-energy wavelengths: Near-Infrared (NIR) photoredox catalysis. Shifting from visible to NIR light brings many advantages including mild reaction conditions and deep penetration of light. These benefits will open novel perspectives in organic synthesis. This present review highlights the recent photocatalytic systems that are able to catalyze challenging organic transformations upon NIR activation.
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ISSN:2052-4110
2052-4110
DOI:10.1039/d1qo01476e