Understanding surface interactions in aqueous miscible organic solvent treated layered double hydroxides

Layered materials are of interest for use in a wealth of technological applications, many of which require a high surface area for optimal properties and performance. Recently, an industrially scalable method to create high surface area layered double hydroxide (LDH) materials, which may be readily...

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Bibliographic Details
Published inRSC advances Vol. 7; no. 9; pp. 576 - 583
Main Authors Erastova, Valentina, Degiacomi, Matteo T, O'Hare, Dermot, Greenwell, H. Chris
Format Journal Article
LanguageEnglish
Published 01.01.2017
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Summary:Layered materials are of interest for use in a wealth of technological applications, many of which require a high surface area for optimal properties and performance. Recently, an industrially scalable method to create high surface area layered double hydroxide (LDH) materials, which may be readily dispersed in non-polar solvents, has been developed. This method involves treatment of LDHs with aqueous miscible organic (AMO) solvents. Here, molecular modeling is exploited to elucidate the AMO solvent-LDH interactions, in order to understand how the dispersion process is facilitated by the AMO treatment. The simulations show how hydrogen-bond networks within the LDH interlayer are disrupted by AMO solvents, leading to delamination. Molecular modelling elucidates the mechanism of layered double hydroxide dispersion, increasing surface area, during aqueous miscible organic solvent treatment.
ISSN:2046-2069
2046-2069
DOI:10.1039/c6ra26834j