PINO/NHPI-mediated selective oxidation of cycloalkenes to cycloalkenones via a photo-electrochemical method

The selective photo-electrochemical oxidation of cyclohexene to 2-cyclohexene-1-one was successfully performed with excellent Faraday efficiency (>99%) via indirect oxidation with a PINO/NHPI mediator and O2 on a BiVO4/WO3 photoanode under low applied bias.

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Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 55; no. 63; pp. 9339 - 9342
Main Authors Tateno, Hiroyuki, Miseki, Yugo, Sayama, Kazuhiro
Format Journal Article
LanguageEnglish
Published England Royal Society of Chemistry 2019
Subjects
Cyclohexene
Electrochemical oxidation
Organic compounds
Oxidation
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Summary:The selective photo-electrochemical oxidation of cyclohexene to 2-cyclohexene-1-one was successfully performed with excellent Faraday efficiency (>99%) via indirect oxidation with a PINO/NHPI mediator and O2 on a BiVO4/WO3 photoanode under low applied bias.
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ISSN:1359-7345
1364-548X
DOI:10.1039/c9cc03540k